By Lieng-Huang Lee (auth.), Lieng-Huang Lee (eds.)
Honolulu is a most pretty position, appropriate for all occa sions. Its selection because the assembly website for the 1st Joint Chemical Congress among the yank Chemical Society and the Chemical Society of Japan was once praised by way of scientists from each side. in this Congress, the foreign convention on Adhesion and Adsorption of Polymers was once held on the Hyatt Regency lodge among April 2 and five, 1979. We had audio system from ten international locations providing over 40 papers on the topic of the subject material. It used to be a memorable occasion. in contrast to our earlier adhesion symposia held in 1971 and 1975, this was once the 1st time within the comparable convention that we mentioned either adhesion and adsorption of polymers at the same time. those very important phenomena should not in basic terms inter-related, but additionally both vital in adhesive know-how in addition to biochemical procedures. The papers provided to this convention take care of those phenomena from either basic and useful viewpoints. in addition, with the improvement of latest floor analytical recommendations, the particular, microscopic happenings on the interfaces might be pin pointed. hence, characterization of interface turned one of many significant focuses of this convention. consequently, a extensive insurance of the subject material contains statistical thermodynamics, floor physics, floor research, fracture mechanics, viscoelasticity, failure research, floor amendment, adsorption kinetics, bio polymer adsorption, and so on. because of the diligence of our contri butors, we're now in a position to post the ultimate papers in those volumes.
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Extra info for Adhesion and Adsorption of Polymers
8. Surface Tension vs. 1/(m+2) for alkylene glycols. 5 Fig. 9. Surface Tension vs. 1/(m+1) for poly (alkylene glycol)s. g. methylene sequence in this case. The difference of the effect of methylene sequence between AG and PAG is probably due to the cooperative adsorption of neighboring sequences in PAG, so that the length of methylene sequence ficti tiously grows to the longer one in the adsorbed states as seen in Fig. 9. The sequence effect is observed more frequently in copolymers as shown in the next section.
Strongly adsorbed to the toluene/water interface than to the air/ water interface, and as a result the effect of pH changes on the adsorbability is screened behind it. On the behavior of ysolfT in the acidic and alkaline end regions, discussions should be reserved at present, because YIlT did not reach equilibrium with time even over 200 hrs. he Figure the values at 100 hrs. ) This is probably due to the dissolution of poly-DL-alanine in toluene in these regions. Anyhow it can be concluded that comparative studies on surface and interfacial tensions are quite useful to make clear the important role of interface and contacting liquid and to characterize the surface behavior of polypeptides in solution.
Ethylene-vinyl acetate copolymers as an example of nonpolar/polar pairs, however, behave considerably differently as shown in Fig. 15, where,( goes through a minimum at about 35 wt% of vinyl acetate. A minimum or a maximum has also been observed in glass transition temperature for some kinds of copolymers, and it has been attempted to modify the additivity law to interpret the results. More theoretically, however, behaviors of polymer surface tension must be founded with liquid theories of polymers, and an explanation for the results of EVA above described has been made by our co-worker, T.
Adhesion and Adsorption of Polymers by Lieng-Huang Lee (auth.), Lieng-Huang Lee (eds.)